System services:
mkdir -p /etc/systemd/system.conf.d/
cat <<"EOF" > /etc/systemd/system.conf.d/override.conf
[Manager]
DefaultEnvironment=FOO=bar
EOF
systemctl daemon-reloadUser services:
mkdir -p "$HOME/.config/systemd/user.conf.d/"
cat <<"EOF" > "$HOME/.config/systemd/user.conf.d/override.conf"
[Manager]
DefaultEnvironment=FOO=bar
EOF
systemctl --user daemon-reload